When does ichigo first get his hollow powers?!

Question: When does ichigo first get his hollow powers!?
Episode 19, when he's getting his powers back!.Www@Enter-QA@Com

Episode 19

title:"Ichigo Becomes a Hollow!"
"Ichigo, horō ni ochiru!" (一護、ホロウに墜ちる!)

summary:In Soul Society Rukia’s sentence is moved up and she only has 25 days left!. In the pit Ichigo battles through the agony of the process of becoming a hollow!. His transformation is almost complete as he enters his own mind, coming face to face with his inner spirit, Zangetsu, who helps him unleash the Soul Reaper powers he was born with!. In a powerful display, Ichigo emerges from the pit with his Soul Reaper uniform on, but also wearing the mask of a hollow!. Breaking the mask off, Ichigo spends the rest of his training fighting Urahara!.


He gets them in Episode 19!. During the Kenpachi Zaraki fight, he apparently uses them in some way (that's not clearly shown) during his training with Zangetsu, as Yoruichi later finds an Ichigo hollow mask there later on!. He doesn't use them in any visible manner until his fight with Byakuya around Ep 55, and he doesn't have the ability to control them until much much later!.Www@Enter-QA@Com

When he fights Byakuya his hollow takes over the battle for a while!.!.!. But before that his mask protects him from 2 fatal blows!.!.!. By Renji and Zaraki!.!.!.!.
When he gains his Shinigami powers back!.!.!. He's only a Shinigami and he didnt even know he had a hollow within him!.!.!. He just battled that inner ichigo to gain control over Zangetsu!.!.Www@Enter-QA@Com

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